Alkali poisoning of Fe-Cu-ZSM-5 catalyst for the selective catalytic reduction of NO with NH3

نویسندگان

چکیده

Fe (2 wt%)-Cu (1.5 wt%)-ZSM-5 SCR catalyst contacted 1.5 wt% of Na and 1.8 K in order to simulate poisoning by species more specifically contained exhaust gases from diesel engines power plants. Poisoning agents do not cause loss surface area nor pore occlusion. XRD SEM results showed that alkali metals introduction did deteriorate the crystallinity morphology zeolite crystals. However, a significant acidity was observed upon alkali-poisoned catalysts causing dramatic deactivation NH3-SCR NO reaction. Na-doped higher low-temperature activity, while potassium has stronger effect on Fe-Cu-ZSM-5 than sodium beyond 400 °C.

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ژورنال

عنوان ژورنال: Research on Chemical Intermediates

سال: 2022

ISSN: ['0922-6168', '1568-5675']

DOI: https://doi.org/10.1007/s11164-022-04768-9